South Pole Antarctica observations and modeling results: New insights on HOx radical and sulfur chemistry

Measurements of OH, H₂SO₄, and MSA at South Pole (SP) Antarctica were recorded as a part of the 2003 Antarctic Chemistry Investigation (ANTCI 2003). The time period 22 November, 2003–2 January, 2004 provided a unique opportunity to observe atmospheric chemistry at SP under both natural conditions as well as those uniquely defined by a solar eclipse event. Results under natural solar conditions generally confirmed those reported previously in the year 2000. In both years the major chemical driver leading to large scale fluctuations in OH was shifts in the concentration levels of NO. Like in 2000, however, the 2003 observational data were systematically lower than model predictions. This can be interpreted as indicating that the model mechanism is still missing a significant HO_x sink reaction(s); or, alternatively, that the OH calibration source may have problems. Still a final possibility could involve the integrity of the OH sampling scheme which involved a fixed building site. As expected, during the peak in the solar eclipse both NO and OH showed large decreases in their respective concentrations. Interestingly, the observational OH profile could only be approximated by the model mechanism upon adding an additional HO_x radical source in the form of snow emissions of CH₂O and/or H₂O₂. This would lead one to think that either CH₂O and/or H₂O₂ snow emissions represent a significant HO_x radical source under summertime conditions at SP. Observations of H₂SO₄ and MSA revealed both species to be present at very low concentrations (e.g., 5 × 10⁵ and 1 × 10⁵ molec cm^?3, respectively), but similar to those reported in 2000. The first measurements of SO₂ at SP demonstrated a close coupling with the oxidation product H₂SO₄. The observed low concentrations of MSA appear to be counter to the most recent thinking by glacio-chemists who have suggested that the plateau's lower atmosphere should have elevated levels of MSA. We speculate here that the absence of MSA may reflect efficient atmospheric removal mechanisms for this species involving either dynamical and/or chemical processes.     

Variations in the Emissions of Volatile Organic Compounds from the Toner for a Specific Photocopier

ABSTRACT

A laboratory thermal desorption apparatus was used to measure emissions from a number of nominally identical photocopier toners—manufactured to meet the specifications of one specific model copier—when these toners were heated to fuser temperature (180-200 °C). The objective was to assess how potential volatile organic compound (VOC) emissions from the toner for a given copier can vary, depending upon the production run and the supplier. Tests were performed on a series of toner (and associated raw polymer feedstock) samples obtained directly from a toner manufacturer, representing two production runs using a nonvented extrusion process, and on toner cartridges purchased from two local retailers, representing three different production lots (histories unknown). The results showed that the retailer toners consistently had up to 350% higher emissions of some major compounds (expressed as |ig of compound emit-ted/g of toner), and up to 100% lower emissions of others, relative to the manufacturer toners (p ≤ 0.01). The manufacturer toners from one production run had emissions of certain compounds, and of total VOCs, that were modestly higher (13-18%) than those from the other run (p ≤ 0.01). The emission differences between the retailer and manufacturer toners are probably due to differences     

The Impact of Gold Smelter Emissions on Vegetation and Soils of a Sub-Arctic Forest-Tundra Transition Ecosystem

Gold smelters near Yellowknife in Canada's Northwest Territories have emitted large quantities of sulfur dioxide and arsenic since inception of roasting in 1941. Although particulate wastes are well contained by baghouse fitters in the one remaining operating smelter, significant gaseous emissions continue. Soil and vegetation were sampled at 52 sites over an area of about 40 km radius from the source. Plant ecology was studied at 43 of those sites. After preliminary multi-element screening that indicated only arsenic was a serious persistent contaminant, x-ray fluorescence was used to measure arsenic content in sampled materials. The plant ecology data were synthesized into an Index of Vitality with numerical ratings of pertinent factors. In the marginal forests and rocky outcrops of the area, indicator species of vegetation permitted a division into zones of severe, moderate, mild, or no impact in order of increasing distance from the current center of emissions. Severe impact, including killing of trees, is local only. Analyses of foliage indicate little uptake of arsenic which, together with the presence of S0₂ symptoms, point to S0₂ as the main factor causing decline of vegetation. A separate study, abstracted here, supports this view by providing data that show a frequency of at least 2 significant fumigation episodes per growing season. Soil analyses indicate extremely high arsenic contamination near the stack. A monotonie pattern of dispersion yielded a function explainable in terms of rapid condensation of gaseous emissions. The relationship of arsenic in surface soil and vegetation to distance is approximately an inverse square.     

Short-term changes in mobile dunes at Port Alfred,South Africa

Development along the western beachfront of Port Alfred, which is situated along a sandy shoreline, increased markedly in the 1960s as the coastal town became a popular holiday resort. This development included the removal of coastal vegetation, which resulted in the destabilization of dunes and migration of sand westerly onto the road, West Beach parking lot, and lawns of the cabanas. Sand traps were constructed to collect sand blowing across the dunes over set periods, and the net sand movement along the mobile dune belt was calculated using Hunter's equation. The dunes show an easterly movement of sand at a rate of 3.5 m/yr, which is comparable with figures recorded along other areas of this coastline. Considering the wind regime and amount of sand movement along this coast, it is inappropriate to clear vegetation and develop within the dune region.     

Vacuum pyrolysis process for remediation of hydrocarbon-contaminated soils

A vacuum pyrolysis process was used for the remediation of hydrocarbon–contaminated soils from “Les Vidangeurs de Montréal” site in Mascouche in the province of Québec, near Montréal. Ten samples were tested on a laboratory scale batch reactor, and one sample was tested on a prototype process development unit. The process is simple, efficient, reliable, and economically competitive with other existing technologies. The vacuum pyrolysis process efficiently treated soils contaminated with a variety of pollution levels and types, irrespective of the soil matrix, providing treated soils meeting the A criterion (noncontaminated, residential level) of the Ministry of Environment Québec (MENVIQ). The pyrolytic oil and the noncondensable pyrolytic gases can be used as makeup fuel in the process, because they have a high calorific value and their combustion should not pose any emission problems. The waterphase effluent must be treated before discharge.     

DOMESTIC WASTEWATER TREATMENT BY PEATLANDS IN A NORTHERN CLIMATE: A WATER QUALITY STUDY1

ABSTRACT: The use of peatlands as the main form of wastewater treatment in a northern climate was studied for the James Bay Energy Society. The Fontanges campsite (70° 17′ 30″ W; 54° 34′ 00″ N) was chosen as the study site. In less than 1.5 km from the point of discharge BOD₅, COD, total hardness, inorganic carbon, orthophosphates, total phosphorus, ammonia and total nitrogen were reduced by at least 90 percent. The peatland treatment system studied is divided into four components, each having a specific function. The first part combines the action of microorganisms and adsorption on peat, thus reducing the organic content while increasing the inorganic constituents. The second part uses peat to adsorb the inorganic elements already present in the wastewater and those produced in the first part of the system. The third component acts as an aerator, increasing the dissolved oxygen and decreasing the BOD₅ levels of the water. The fourth part removes most of the remaining nutrients, thus acting like a tertiary treatment. Overall, peatlands seemed to be effective in treating domestic settled wastewater in a cold climate.     

VELOCITY EQUATION FOR WATER QUALITY MODELING IN GEORGIA1

ABSTRACT: Tabletop water quality modeling still plays an important role in the water pollution control activities of the Georgia Environmental Protection Division. Tabletop models are those developed with out the aid of extensive field data. One important component of GEORGIA DOSAG, our basic water quality model, is the equation used to predict flow through velocity. However, Georgia is characterized by wide physiographic diversity which reduces the effectiveness of uncalibrated velocity equations. Using 15 years of accumulated time-of-travel studies, a series of empirical velocity equations were developed and calibrated to various physiographic conditions in Georgia. Equations are available for each major soil province and for three stream flow ranges within each province - Q<100 cfs, 100<Q<1000 cfs, and Q>1000 cfs. Now, in the absence of extensive field data, we have data based velocity equations which can be tailored to each site under study.     

MULTICRITERIA PROGRAMMING OF WATER SUPPLY SYSTEMS FOR RURAL AREAS1

ABSTRACT: The aim of this paper is to present a multicriteria methodology for decision aid at the stage of programming a water supply system (WSS) for a rural area. The programming stage is an intermediate one between planning and designing water supply facilities, and can be decomposed into two problems: (a) setting up a priority order of water users, taking into account socio-economic criteria; and (b) choosing the best technical variant of the WSS. Among the criteria considered for the latter problem, there is a criterion of distance between the socio-economic priorities of users and the precedence orders of users according to the technical programming, which plays a coordinating role between problems (a) and (b). All steps of the presented methodology are illustrated by a real case study.     

WATER RESOURCES AND SOCIAL CHOICES1

ABSTRACT The problem of water resources management can be viewed as one requiring the existence and application of some type of “collective decision” mechanism. Currently, the general water resource decision problem is solved using an “individual decision” format without explicit consideration of the dominant social decision system. This paper demonstrates the need for blending technical planning activities with organized societal processes and then proposes a specific public decision framework to satisfy this requirement. The key element in this planning framework is a generalized “bargaining arena” which serves to link technical activities with the social system. Using this bargaining device we can (1) specify policy at a local level, (2) incorporate “social decision” rules into the planning process, and (3) provide local access to the decision process. A simple case of regional water quality management is used to describe the application of this planning procedure and to offer encouragement for successful use in more complex real-world cases.     

Correlations in the chemical composition of rural background atmospheric aerosol in the UK determined in real time using time-of-flight mass spectrometry

An aerosol time-of-flight mass spectrometer (ATOFMS) was used to determine, in real time, the size and chemical composition of individual particles in the atmosphere at the remote inland site of Eskdalemuir, Scotland. A total of 51,980 particles, in the size range 0.3-7.4 microm, were detected between the 25th and 30th June 2001. Rapid changes in the number density, size and chemical composition of the atmospheric aerosol were observed. These changes are attributed to two distinct types of air mass; a polluted air mass that had passed over the British mainland before reaching Eskdalemuir, interposed between two cleaner air masses that had arrived directly from the sea. Such changes in the background aerosol could clearly be very important to studies of urban aerosols and attempts at source apportionment. The results of an objective method of data analysis are presented. Correlations were sought between the occurrence of: lithium, potassium, rubidium, caesium, beryllium, strontium, barium, ammonium, amines, nitrate, nitrite, boron, mercury, sulfate, phosphate, fluorine, chlorine, bromine, iodine and carbon (both elemental and organic hydrocarbon) in both fine (d < 2.5 microm) and coarse (d > 2.5 microm) particle fractions. Several previously unreported correlations were observed, for instance between the elements lithium, beryllium and boron. The results suggest that about 2 in 3 of all fine particles (by number rather than by mass), and 1 in 2 of all coarse particles containing carbon, consisted of elemental carbon rather than organic hydrocarbon (although a bias in the sensitivity of the ATOFMS could have affected these numbers). The ratio of the number of coarse particles containing nitrate anions to the number of particles containing chloride anions exceeded unity when the air mass had travelled over the British mainland. The analysis also illustrates that an air mass of marine origin that had travelled slowly over agricultural land can accumulate amines and ammonium.